OPEN ACCESS

Articles online

Diurnal Variability in Secondary Organic Aerosol Formation over the Indo-Gangetic Plain during Winter Using Online Measurement of Water-Soluble Organic Carbon

Category: Physical and Chemical Characteristics of Aerosols

Volume: 15 | Issue: 6 | Pages: 2225-2231
DOI: 10.4209/aaqr.2015.02.0097
PDF | RIS | BibTeX

Neeraj Rastogi 1, Anil Patel1, Atinderpal Singh2, Darshan Singh2

  • 1 Geosciences Division, Physical Research Laboratory, Ahmedabad, India
  • 2 Department of Physics, Punjabi University, Patiala, Punjab, India

Highlights

First online WSOC measurement over India reveals its diurnal characteristics.

Secondary WSOC dominates the total WSOC concentration with ~80% contribution.

Considerable SOA formation was observed during 7:00 to 22:00 hrs.

A significant fraction of fine particles is SOA over the IGP during winter.


Abstract

Understanding the secondary organic aerosol (SOA) formation is among most important topics in the field of aerosol research because its poor understanding leads to large uncertainty in the assessment of aerosol effects on air quality and climate. This study reports the diurnal and temporal variability in SOA formation over a site (Patiala: 30.2°N, 76.3°E, 249 m amsl) located in the Indo-Gangetic Plain (IGP) during winter using the first online measurements of water-soluble organic carbon (WSOC) over India. Online WSOC, measured with particle-into-liquid sampler (PILS) connected to total organic carbon (TOC) analyzer, ranged from 0.1 to 99 µg m3 (avg: 15.6, sd: 9.4) with a considerable day-to-day and within the day variability, and attributed to meteorological conditions and regional sources. Diurnal trends of online WSOC suggest significant SOA formation during 7:00 to 22:00 hrs when sources of SOA precursors are active; and loss of SOA occurs during afternoon when ambient air temperature is at its peak. In parallel to online measurements, filter-based particulate matter smaller than 2.5 µm (PM2.5) samples were also collected and analyzed for major cations, anions and carbonaceous aerosols. Filter-based PM2.5 composition suggests that the emissions from biomass burning contribute more to carbonaceous aerosols than those from fossil fuel burning. In spite of this, average primary WSOC was only ~20% whereas secondary WSOC (or SOA) dominated the total WSOC concentration with ~80% contribution. A strong linear relationship between PM1 and WSOC (R2 = 0.83, slope = 0.113, intercept = 4.7), suggests that a significant fraction of fine particles are SOA.

Keywords

Biomass burning SOA Carbonaceous aerosols: WSOC India


Related Article

An Investigation of the Variability of Particulate Emissions from Woodstoves in New Zealand

Guy Coulson , Richard Bian, Elizabeth Somervell
Volume: 15 | Issue: 6 | Pages: 2346-2356
DOI: 10.4209/aaqr.2015.02.0111
PDF

A Long Term Study on Characterization and Source Apportionment of Particulate Pollution in Klang Valley, Kuala Lumpur

Shamsiah Abdul Rahman , Mohd Suhaimi Hamzah, Md Suhaimi Elias, Nazaratul Ashifa Abdullah Salim, Azian Hashim, Shakirah Shukor, Wee Boon Siong, Abdul Khalik Wood
Volume: 15 | Issue: 6 | Pages: 2291-2304
DOI: 10.4209/aaqr.2015.03.0188
PDF | Supplemental material