Volume 12, No. 4, August 2012, Pages 536-543 PDF(217 KB)
Source Apportionment of PM2.5 in a Subarctic Airshed - Fairbanks, Alaska
Tony Ward1, Barbara Trost2, Jim Conner3, James Flanagan4, R.K.M. Jayanty4
1 Center for Environmental Health Sciences, The University of Montana, Missoula, Montana, USA
2 Alaska Department of Environmental Conservation, Anchorage, Alaska, USA
3 Fairbanks North Star Borough, Fairbanks, Alaska, USA
4 RTI International, Research Triangle Park, North Carolina, USA
Fairbanks, Alaska has some of the highest measured ambient PM2.5 concentrations in the United States, with wintertime levels often exceeding the 24-hour PM2.5 National Ambient Air Quality Standard (NAAQS) of 35 µg/m3. In an effort to understand the sources of PM2.5 in the Fairbanks airshed, source apportionment using Chemical Mass Balance (CMB) modeling was conducted at four locations in Fairbanks over a three-winter period (2008/2009, 2009/2010, and 2010/2011).
At each of the four sites, PM2.5 concentrations averaged between 22.5 ± 12.0 µg/m3 and 26.5 ± 18.9 µg/m3, with frequent exceedances of the 24-hour NAAQS on the scheduled sample days. The results of the CMB modeling revealed that wood smoke (likely residential wood combustion) was the major source of PM2.5 throughout the winter months in Fairbanks, contributing between 60% and nearly 80% of the measured PM2.5 at the four sites. The other sources of PM2.5 identified by the CMB model were secondary sulfate (8–20%), ammonium nitrate (3–11%), diesel exhaust (not detected-10%), and automobiles (not detected-7%). Approximately 1% of the PM2.55 was unexplained by the CMB model. Additional research is needed to confirm the woodsmoke results of the CMB model, as well as determine which sources (fuel oil residential heating, coal combustion, etc.) contribute to the measured secondary sulfate.
Chemical Mass Balance; Woodstoves; Source apportionment; Biomass smoke, PM2.5.