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Volume 13, No. 1, February 2013, Pages 407-414 PDF(296 KB)  
doi: 10.4209/aaqr.2012.05.0130   

Autumn and Wintertime Polycyclic Aromatic Hydrocarbons in PM2.5 and PM2.5–10 from Urumqi, China

Yi Li Mire A Bu Da Limu1, Di Li Nuer Ta LiFu1, A Bu Lizi Yi Miti1, Xinming Wang2, Xiang Ding2

1 College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi, Xinjiang 830046, China
2 State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry Chinese Academy of Sciences, Guangzhou 510640, China




Concurrent sampling of PM2.5 and PM2.5–10 aerosols on a rooftop (15 m above ground) was conducted at a location in urban Urumqi (Xinjiang University 43°77'N, 87°61'E) during September 2010 to March 2011. These filters were analyzed for fifteen polycyclic aromatic hydrocarbons (PAHs). The ΣPAHs (sum of 15 PAHs) ranged from 0.11 to 1058.08 ng/m3 in PM2.5 and 0.01 to 90.89 ng/m3 in PM2.5–10, respectively. 90% of the ΣPAHs existed in PM2.5. In the autumn the ΣPAHs ranged from an undetectable level to 10.93 ng/m3 in PM2.5 and 2.10 ng/m3 in PM2.5–10, and in the winter from an undetectable level to 54.11 ng/m3 in PM2.5 and 5.12 ng/m3 in PM2.5–10.
    Benzo(a)pyrene-equivalent carcinogenic potency (BaPeq) was calculated to evaluate the cancer risk of carcinogenic PAHs to the public. The level of BaPeq in PM2.5 was an average of 5.97 ng/m3, significantly higher than the value recommended by the WTO (1 ng/m3). This suggests that it is important to control regional combustion sources to reduce air pollution-related health risks in urban Urumqi.



Keywords: Fine particulate (PM2.5); Coarse particulate (PM2.5–10); PAHs Source apportionment; Urumqi.



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