Volume 17, No. 3, March 2017, Pages 653-665 PDF(1.62 MB)
Supplementary MaterialPDF (332 KB)
Transformations of Aerosol Particles from an Outdoor to Indoor Environment
Nicholas Talbot1,2, Lucie Kubelová1,2, Otakar Makeš1,2, Jakub Ondráček1, Michael Cusack1, Jaroslav Schwarz1, Petr Vodička1, Naděžda Zíková1, Vladimír Ždímal1
1 Institute of Chemical Process Fundamentals of the CAS, v.v.i., Rozvojová 2, Prague 165 02, Czech Republic
2 Charles University, Faculty of Science, Department of Environmental Studies, Prague, 128 43, Czech Republic
- Particle shrinkage observed indoors during winter campaign.
- I/O ratios were lower for all chemical species during winter.
- I/O temperature gradient increased NH4NO3 losses.
- BLPI measured less NH4NO3 indoors than AMS.
- Wind speed and direction correlated to I/O ratios.
2017/02/09Aerosol particle size and chemical composition during summer and winter were investigated in this study. An automated switching valve allowed for indoor and outdoor environments to be sampled near-simultaneously with the same high temporal-resolution instrumentation. During the study, no known indoor sources were present and the sampled room was unoccupied throughout.
Accumulation mode indoor/outdoor (I/O) ratios were substantially lower in winter than in summer. This reduction was attributed to particles of outdoor origin shrinking as they entered the warmer and drier indoor environment. An essential factor in this process appeared to be the difference (gradient) between the temperature and relative humidity of the indoor and outdoor environments during the winter. Online aerosol mass spectrometer measurements recorded a 34–38% decrease in I/O ratios for all nonrefractory species during the winter relative to the summer. A similar change in I/O ratios for all species indicated that physical, rather than chemical, processes were responsible.
To assess the relative influence of various physical factors on I/O relationships, Spearman rank statistical tests were carried out. These identified wind speed to be negatively correlated to the indoor concentrations for all species. Wind roses incorporating I/O ratios were applied and showed that the wind speed and direction influenced the changes in the indoor composition. The relative outdoor concentration of different aerosol species, steepness of the I/O temperature gradient, and wind speed variability are concluded to be essential factors in I/O aerosol transformations.
I/O ratio; Shrinkage; Dissociation; Aerosols; Ammonium nitrate